Genesis of the electronic spectrum and magnetic properties of a high-temperature phase of nonstoichiometric strontium ferrite SrFeO3–δ (0 ≤ δ ≤ 0.5)

Resumo

The genesis of the electronic spectrum and magnetic properties of a high-temperature cubic phase of SrFeO_3–δ with the disordered distribution of oxygen vacancies under the variation of their concentration has been studied in the coherent-potential approximation within the LDA + U formalism. Experimental tendencies of the fundamental electron-energy and magnetic characteristics in SrFeO_3–δ under the variation of oxygen nonstoichiometry within the homogeneity region, 0 ≤ δ ≤ 0.5, have been described.