Photostimulated oxidation of water catalyzed by a tetranuclear ruthenium complex with lithium countercations
- Авторы: Dzhabieva Z.M.1, Tkachenko V.Y.1, Dzhabiev T.S.1
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Учреждения:
- Institute of Problems of Chemical Physics
- Выпуск: Том 51, № 3 (2017)
- Страницы: 215-218
- Раздел: Photochemistry
- URL: https://bakhtiniada.ru/0018-1439/article/view/157188
- DOI: https://doi.org/10.1134/S0018143917030043
- ID: 157188
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Аннотация
Photostimulated oxidation of water by potassium persulfate in the presence of photosensitizer bpy3RuCl2 ∙ 6H2O and ruthenium catalyst Li10[{Ru4(μ-O)4(μ-OH)2(H2O)4} ∙ (γ-SiW10O36)2] ∙ 10H2O has been studied. It has been shown that the quantum yield of O2 (0.29) is much higher than the quantum yield in a similar photocatalytic system with rubidium countercations (0.09).
Об авторах
Z. Dzhabieva
Institute of Problems of Chemical Physics
Email: timur@cat.icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
V. Tkachenko
Institute of Problems of Chemical Physics
Email: timur@cat.icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
T. Dzhabiev
Institute of Problems of Chemical Physics
Автор, ответственный за переписку.
Email: timur@cat.icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
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