1,4-dithiane radical cations in the CF3CCl3 matrix: Photoisomerization mechanism
- Autores: Sorokin I.D.1, Gromov O.I.1,2, Pergushov V.I.1, Melnikov M.Y.1
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Afiliações:
- Department of Chemistry
- N.N. Semenov Institute of Chemical Physics
- Edição: Volume 50, Nº 5 (2016)
- Páginas: 362-367
- Seção: Photochemistry
- URL: https://bakhtiniada.ru/0018-1439/article/view/157041
- DOI: https://doi.org/10.1134/S0018143916050155
- ID: 157041
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Resumo
It has been established that the photoinduced process observed in EPR and in optical absorption spectra for 1,4-dithiane radical cations in the CF3CCl3 matrix at 77 K can be ascribed to a “boat”—“twist boat” conformational transition.
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Sobre autores
I. Sorokin
Department of Chemistry
Autor responsável pela correspondência
Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991
O. Gromov
Department of Chemistry; N.N. Semenov Institute of Chemical Physics
Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991; Kosygina street, 4, Moscow, 119991
V. Pergushov
Department of Chemistry
Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991
M. Melnikov
Department of Chemistry
Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991
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