1,4-dithiane radical cations in the CF3CCl3 matrix: Photoisomerization mechanism


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It has been established that the photoinduced process observed in EPR and in optical absorption spectra for 1,4-dithiane radical cations in the CF3CCl3 matrix at 77 K can be ascribed to a “boat”—“twist boat” conformational transition.

Sobre autores

I. Sorokin

Department of Chemistry

Autor responsável pela correspondência
Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991

O. Gromov

Department of Chemistry; N.N. Semenov Institute of Chemical Physics

Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991; Kosygina street, 4, Moscow, 119991

V. Pergushov

Department of Chemistry

Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991

M. Melnikov

Department of Chemistry

Email: ivan.d.sorokin@gmail.com
Rússia, Leninskiye gory, 1/3, Moscow, 119991

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