Posteffects of photoreduction of graphene oxide films


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Аннотация

The dark process (posteffect) of increasing the electrical conductivity and spectral absorption in the graphene oxide (GO) film after its preliminary UV irradiation has been studied. The posteffect is due to the conformational relaxation of the structure (flattening) of GO nanosheets after the UV-induced dissociation of oxygen-containing groups. At room temperature, the relaxation time is τ ≈ 300 h and the activation energy in the range of 20–70°C is Ea ≈ 0.6 eV.

Авторлар туралы

V. Smirnov

Institute of Problems of Chemical Physics; Tomsk State University

Хат алмасуға жауапты Автор.
Email: vas@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Tomsk, 634050

V. Plotnikov

Tomsk State University; Photochemistry Center

Email: vas@icp.ac.ru
Ресей, Tomsk, 634050; Moscow, 119421

A. Mokrushin

Institute of Microelectronics Technology and High Purity Materials

Email: vas@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432

E. Egorov

Institute of Microelectronics Technology and High Purity Materials

Email: vas@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432

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