Pyrazolyltetrazoles—a High-Enthalpy Backbone for Designing High-Energy Compounds: An Experimental Study of the Enthalpy of Formation

A. I. Kazakov; L. S. Kurochkina; A. V. Nabatova; D. B. Lempert; I. L. Dalinger; A. V. Kormanov; O. V. Serushkina; A. B. Sheremetev

doi:10.1134/S0012501618010049

Pyrazolyltetrazoles—a High-Enthalpy Backbone for Designing High-Energy Compounds: An Experimental Study of the Enthalpy of Formation

Авторы: Kazakov A.I.¹, Kurochkina L.S.¹, Nabatova A.V.¹, Lempert D.B.¹, Dalinger I.L.², Kormanov A.V.², Serushkina O.V.², Sheremetev A.B.²
Учреждения:
1. Institute of Problems of Chemical Physics
2. Zelinskii Institute of Organic Chemistry
Выпуск: Том 478, № 1 (2018)
Страницы: 15-18
Раздел: Physical Chemistry
URL: https://bakhtiniada.ru/0012-5016/article/view/153814
DOI: https://doi.org/10.1134/S0012501618010049
ID: 153814

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The standard enthalpies of combustion and formation of isomeric nitropyrazolyltetrazoles have been measured by combustion calorimetry. Positional isomerism has been shown to have a significant effect on thermochemical characteristics. The contributions of some explosophore groups and moieties to the total heat content of the molecules have been determined. These contributions can be used to correctly calculate the enthalpy of formation of both known and hypothetical energy-intensive compounds.