Electron–nuclear motions in a series of meta-substituted iodobenzene derivatives as probed by  127 I NQR

G. K. Semin; S. I. Gushchin; E. V. Semina; S. I. Kuznetsov; V. M. Burbelo

doi:10.1134/S0012500816110069

Electron–nuclear motions in a series of meta-substituted iodobenzene derivatives as probed by ¹²⁷I NQR

Autores: Semin G.K.¹, Gushchin S.I.², Semina E.V.¹, Kuznetsov S.I.¹, Burbelo V.M.¹
Afiliações:
1. Nesmeyanov Institute of Organoelement Compounds
2. Perm State University
Edição: Volume 471, Nº 1 (2016)
Páginas: 325-329
Seção: Chemistry
URL: https://bakhtiniada.ru/0012-5008/article/view/153815
DOI: https://doi.org/10.1134/S0012500816110069
ID: 153815

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Resumo

A relation between the quadrupole coupling constant e²Qq_zz and asymmetry parameter η has been found for a series of meta-substituted iodobenzene derivatives. The relationships e²Qq_zz(η) for electrondonor and electron-acceptor substituents have the same form but different numerical values of parameters. The average time of full electron transfer via tunneling has been evaluated.